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Thermal radiative properties of metamaterials and other nanostructured materials: A review

Ceji FU, Zhuomin M. ZHANG

《能源前沿(英文)》 2009年 第3卷 第1期   页码 11-26 doi: 10.1007/s11708-009-0009-x

摘要: The ability to manufacture, control, and manipulate structures at extremely small scales is the hallmark of modern technologies, including microelectronics, MEMS/NEMS, and nano-biotechnology. Along with the advancement of microfabrication technology, more and more investigations have been performed in recent years to understand the influence of microstructures on radiative properties. The key to the enhancement of performance is through the modification of the reflection and transmission properties of electromagnetic waves and thermal emission spectra using one-, two-, or three-dimensional micro/nanostructures. This review focuses on recent developments in metamaterials–manmade materials with exotic optical properties, and other nanostructured materials, such as gratings and photonic crystals, for application in radiative energy transfer and energy conversion systems.

关键词: metamaterial     nanostructured material     thermal radiative property     radiative energy transfer    

novel strategy for the construction of silk fibroin–SiO composite aerogel with enhanced mechanical propertyand thermal insulation performance

《化学科学与工程前沿(英文)》 2023年 第17卷 第3期   页码 288-297 doi: 10.1007/s11705-022-2222-7

摘要: The practical application of silica aerogels is an enormous challenge due to the difficulties in improving both mechanical property and thermal insulation performance. In this work, silk fibroin was used as scaffold to improve the mechanical property and thermal insulation performance of silica aerogels. The ungelled SiO2 precursor solution was impregnated into silk fibroin to prepare silk fibroin–SiO2 composite aerogels via sol−gel method followed by freeze-drying. By virtue of the interfacial hydrogen-bonding interactions and chemical reactions between silk fibroin and silica nanoparticles, SiO2 was well-dispersed in the silk fibroin aerogel and composite aerogels exhibited enhanced mechanical property. By increasing the loading of silk fibroin from 15 wt % to 21 wt %, the maximum compressive stress was enhanced from 0.266 to 0.508 MPa when the strain reached 50%. The thermal insulation performance of the composite aerogels was improved compared with pure silica aerogel, as evidenced that the thermal conductivity was decreased from 0.0668 to 0.0341 W∙m‒1∙K‒1. Moreover, the composite aerogels exhibited better hydrophobicity and fire retardancy compared to pure silica aerogel. Our work provides a novel approach to preparing silk fibroin–SiO2 composite aerogels with enhanced mechanical property and thermal insulation performance, which has potential application as thermal insulation material.

关键词: silica aerogel     silk fibroin     impregnation     thermal insulation     mechanical property    

Adsorption property of direct fast black onto acid-thermal modified sepiolite and optimization of adsorption

Chengyuan SU, Weiguang LI, Yong WANG

《环境科学与工程前沿(英文)》 2013年 第7卷 第4期   页码 503-511 doi: 10.1007/s11783-012-0477-9

摘要: The adsorption of direct fast black onto acid-thermal modified sepiolite was investigated. Batch adsorption experiments were performed to evaluate the influences of experimental parameters such as initial dye concentration, initial solution pH and adsorbent dosage on the adsorption process. The three-factor and three-level Box-Behnken response surface methodology (RSM) was utilized for modeling and optimization of the adsorption conditions for direct fast black onto the acid-thermal modified sepiolite. The raw sepiolite was converted to acid-thermal modified sepiolite, and changes in the fourier transform infrared spectrum (FTIR) adsorption bands of the sample were noted at 3435 cm and 1427 cm . The zeolitic water disappeared and the purity of sepiolite was improved by acid-thermal modification. The decolorization rate of direct fast black adsorbed increased from 68.2% to 98.9% on acid-thermal modified sepiolite as the initial solution pH decreased from 10 to 2. When the adsorbent dosage reached to 2.5 g·L , 2.0 g·L , 1.5 g·L and 1.0 g·L , the decolorization rate was 90.3%, 86.7%, 61.0% and 29.8%, respectively. When initial dye concentration increased from 25 to 200 mg·L , the decolorization rate decreased from 91.9% to 60.0%. The RSM results showed that the interaction between adsorbent dosage and pH to be a significant factor. The optimum conditions were as follows: the adsorbent dosage 1.99 g·L , pH 4.22, and reaction time 5.2 h. Under these conditions, the decolorization rate was 95.1%. The three dimensional fluorescence spectra of direct fast black before and after treatment showed that the direct fast black was almost all adsorbed by the acid-thermal modified sepiolite.

关键词: direct fast black     acid-thermal modified sepiolite     adsorption     response surface methodology    

Thermal performance of a single-layer packed metal pebble-bed exposed to high energy fluxes

Shengchun ZHANG, Zhifeng WANG, Hui BIAN, Pingrui HUANG

《能源前沿(英文)》 2021年 第15卷 第2期   页码 513-528 doi: 10.1007/s11708-019-0638-7

摘要: It is difficult to accurately measure the temperature of the falling particle receiver since thermocouples may directly be exposed to the solar flux. This study analyzes the thermal performance of a packed bed receiver using large metal spheres to minimize the measurement error of particle temperature with the sphere temperature reaching more than 700°C in experiments in a solar furnace and a solar simulator. The numerical models of a single sphere and multiple spheres are verified by the experiments. The multiple spheres model includes calculations of the external incidence, view factors, and heat transfer. The effects of parameters on the temperature variations of the spheres, the transient thermal efficiency, and the temperature uniformity are investigated, such as the ambient temperature, particle thermal conductivity, energy flux, sphere diameter, and sphere emissivity. When the convection is not considered, the results show that the sphere emissivity has a significant influence on the transient thermal efficiency and that the temperature uniformity is strongly affected by the energy flux, sphere diameter, and sphere emissivity. As the emissivity increases from 0.5 to 0.9, the transient thermal efficiency and the average temperature variance increase from 53.5% to 75.7% and from 14.3% to 27.1% at 3.9 min, respectively. The average temperature variance decreases from 29.7% to 9.3% at 2.2 min with the sphere diameter increasing from 28.57 mm to 50 mm. As the dimensionless energy flux increases from 0.8 to 1.2, the average temperature variance increases from 13.4% to 26.6% at 3.4 min.

关键词: packed bed     solar thermal power plants     high heat fluxes     radiative heat transfer    

Dielectric property of polyimide/barium titanate composites and its influence factors (II)

LIU Weidong, ZHU Baoku, XIE Shuhui, XU Zhikang

《化学科学与工程前沿(英文)》 2008年 第2卷 第4期   页码 417-421 doi: 10.1007/s11705-008-0078-0

摘要: Using poly(amic acid) (PAA) as a precursor followed by thermal imidization, the polyimide/barium titanate composite films were successfully prepared by a direct mixing method and in situ process. The influence of processing factors, such as particle size, distribution mode and polymerization method on dielectric properties was studied. Results revealed that the dielectric constant (?) of the composite film increased by using bigger fillers or employing in situ polymerization and bimodal distribution. When the composite film containing 50 Vol-% of BaTiO with size in 100 nm was prepared via in situ process, its dielectric constant reached 45 at 10 kHz.

关键词: thermal imidization     dielectric constant     particle     precursor     titanate composite    

基于蝶翅三级微纳米结构的定制光子工程辐射制冷纺织品 Article

郭竑宇, 牛田野, 俞建勇, 王学利, 斯阳

《工程(英文)》 2023年 第31卷 第12期   页码 120-126 doi: 10.1016/j.eng.2023.07.019

摘要:

通过将被动辐射制冷策略与个人热管理技术相结合,为缓解人体在户外活动中的热不适感提供了新的思路。然而,目前大多数被动辐射制冷材料在穿着舒适性和耐用性方面存在不足。本文采用微阵列技术,成功制备出了具有辐射制冷能力的定制光子工程可穿戴纺织品。所开发的辐射制冷纺织品(RCTs)具有一定的透气透湿性、结构稳定性和扩展光谱响应性(太阳光反射率91.7%、大气窗口发射率95.8%)。在正午炎热环境的室外降温测试中,RCTs所覆盖的皮肤模拟器温度比棉织物低4.4 ℃。这种仿生结构的开发为可穿戴、热湿舒适和结构稳定的辐射制冷纺织品在个人热管理领域的应用提供了新的见解。

关键词: 仿生材料     个人热管理     纺织品     辐射制冷    

of hierarchical nanohybrid CNT@Ni-PS and its applications in enhancing the tribological, curing and thermal

Jinian Yang, Yuxuan Xu, Chang Su, Shibin Nie, Zhenyu Li

《化学科学与工程前沿(英文)》 2021年 第15卷 第5期   页码 1281-1295 doi: 10.1007/s11705-020-2007-9

摘要: Poor interfacial adhesion and dispersity severely obstruct the continued development of carbon nanotube (CNT)-reinforced epoxy (EP) for potential applications. Herein, hierarchical CNT nanohybrids using nickel phyllosilicate (Ni-PS) as surface decorations (CNT@Ni-PS) were synthesized, and the nanocomposites derived from varied mass fractions of EP and CNT@Ni-PS were prepared. The morphological structures, tribological performances, curing behaviors and thermal properties of EP/CNT@Ni-PS nanocomposites were carefully investigated. Results show that hierarchical CNT nanohybrids with homogeneous dispersion and well-bonded interfacial adhesion in the matrix are successfully obtained, presenting significantly improved thermal and tribological properties. Moreover, analysis on cure kinetics proves the excellent promotion of CNT@Ni-PS on the non-isothermal curing process, lowering the curing energy barrier steadily.

关键词: nickel phyllosilicate     surface decoration     tribological property     curing kinetics     thermal performance    

Microdamage study of granite under thermomechanical coupling based on the particle flow code

《结构与土木工程前沿(英文)》   页码 1413-1427 doi: 10.1007/s11709-023-0953-2

摘要: The thermomechanical coupling of rocks refers to the interaction between the mechanical and thermodynamic behaviors of rocks induced by temperature changes. The study of this coupling interaction is essential for understanding the mechanical and thermodynamic properties of the surrounding rocks in underground engineering. In this study, an improved temperature-dependent linear parallel bond model is introduced under the framework of a particle flow simulation. A series of numerical thermomechanical coupling tests are then conducted to calibrate the micro-parameters of the proposed model by considering the mechanical behavior of the rock under different thermomechanical loadings. Good agreement between the numerical results and experimental data are obtained, particularly in terms of the compression, tension, and elastic responses of granite. With this improved model, the thermodynamic response and underlying cracking behavior of a deep-buried tunnel under different thermal loading conditions are investigated and discussed in detail.

关键词: thermomechanical coupling effect     granite     improved linear parallel bond model     thermal property     particle flow code    

A spectrally selective surface structure for combined photothermic conversion and radiative sky cooling

Bin ZHAO, Xianze AO, Nuo CHEN, Qingdong XUAN, Mingke HU, Gang PEI

《能源前沿(英文)》 2020年 第14卷 第4期   页码 882-888 doi: 10.1007/s11708-020-0694-z

摘要: The sun and outer space are the ultimate heat and cold sources for the earth, respectively. They have significant potential for renewable energy harvesting. In this paper, a spectrally selective surface structure that has a planar polydimethylsiloxane layer covering a solar absorber is conceptually proposed and optically designed for the combination of photothermic conversion (PT) and nighttime radiative sky cooling (RC). An optical simulation is conducted whose result shows that the designed surface structure (i.e., PT-RC surface structure) has a strong solar absorption coefficient of 0.92 and simultaneously emits as a mid-infrared spectral-selective emitter with an average emissivity of 0.84 within the atmospheric window. A thermal analysis prediction reveals that the designed PT-RC surface structure can be heated to 79.1°C higher than the ambient temperature in the daytime and passively cooled below the ambient temperature of approximately 10°C in the nighttime, indicating that the designed PT-RC surface structure has the potential for integrated PT conversion and nighttime RC utilization.

关键词: solar energy     photothermic conversion     radiative sky cooling     spectral selectivity     multilayer film    

用于个人降温和保暖的具有定制热传导和热辐射特性的双功能非对称织物 Article

Yucan Peng, Hiang Kwee Lee, David S. Wu, Yi Cui

《工程(英文)》 2022年 第10卷 第3期   页码 167-173 doi: 10.1016/j.eng.2021.04.016

摘要:

为了让人体感到热舒适,同时节约能源,个人热管理正逐渐成为一种颇有前景的策略。通过更好地控制人体散热,个人热管理可以实现有效的个人降温和保暖。本文提出了一种简单的表面改性方法,在商用织物的基础上定制热传导和热辐射特性,以便更好地管理从人体到环境的整个传热路径。本文对一种同时具有降温和保暖效果的双功能非对称织物(BAF)进行论证。凭借粗糙度不对称和表面改性等优点,BAF在降温模式下通过增强热传导和热辐射表现出显著的降温效果;在保暖模式下,两条路径的散热都减少,从而实现个人保暖。结果表明,在BAF的降温和保暖模式下测得的皮肤温差可达4.6 ℃,表明一件BAF衣服可以扩大人体的热舒适区。希望本研究可为用于个人热管理的织物的设计提供新的视角,并为现有的用于个人降温和保暖的织物的简单改性提供新的解决方案。

关键词: 织物     个人热管理     双功能非对称织物     热传导     热辐射    

Entropy flow, entropy generation, exergy flux, and optimal absorbing temperature in radiative transfer

Zeshao CHEN, Songping MO, Peng HU, Shouli JIANG, Gang WANG, Xiaofang CHENG,

《能源前沿(英文)》 2010年 第4卷 第3期   页码 301-305 doi: 10.1007/s11708-010-0006-0

摘要: Taking nonequilibrium radiative heat transfer between two surfaces as an example, the nonequilibrium thermodynamics of radiation is studied and discussed. The formulas of entropy flow, entropy generation, exergy flux, and optimal temperature of absorbing surface for maximum exergy output are derived. The result is a contribution to the thermodynamic analysis and optimization of solar energy utilization and can be applied in more complex radiative heat transfer cases.

关键词: radiative heat transfer     entropy generation     exergy     thermodynamics    

Modeling radiative effects of haze on summer-time convective precipitation over North China: a case study

Xuying WANG, Bin ZHANG

《环境科学与工程前沿(英文)》 2016年 第10卷 第4期 doi: 10.1007/s11783-016-0840-3

摘要: We modeled the impact of haze radiative effects on precipitation in North China. Shortwave heating induced by haze radiative effects would reduce heavy rainfalls. Convection was the key factor that whether precipitation was enhanced or suppressed. Precipitation was often suppressed where CAPE, RH and updraft velocities were high. The impact of haze radiative effect on summertime 24-h convective precipitation over North China was investigated using WRF model (version 3.3) through model sensitivity studies between scenarios with and without aerosol radiative effects. The haze radiative effect was represented by incorporating an idealized aerosol optical profile, with AOD values around 1, derived from the aircraft measurement into the WRF shortwave scheme. We found that the shortwave heating induced by aerosol radiative effects would significantly reduce heavy rainfalls, although its effect on the post-frontal localized thunderstorm precipitation was more diverse. To capture the key factors that determine whether precipitation is enhanced or suppressed, model grids with 24-h precipitation difference between the two scenarios exceeding certain threshold (>30 mm or<-30 mm) were separated into two sets. Analyses of key meteorological variables between the enhanced and suppressed regimes suggested that atmospheric convection was the most important factor that determined whether precipitation was enhanced or suppressed during summertime over North China. The convection was stronger over places with precipitation enhancement over 30 mm. Haze weakened the convection over places with precipitation suppression exceeding 30 mm and caused less water vapor to rise to a higher level and thus further suppressed precipitation. The suppression of precipitation was often accompanied with relatively high convective available potential energy (CAPE), relative humidity (RH) and updraft velocities.

关键词: Haze     Aerosol radiative effects     Convective precipitation    

Modeling process-structure-property relationships for additive manufacturing

Wentao YAN, Stephen LIN, Orion L. KAFKA, Cheng YU, Zeliang LIU, Yanping LIAN, Sarah WOLFF, Jian CAO, Gregory J. WAGNER, Wing Kam LIU

《机械工程前沿(英文)》 2018年 第13卷 第4期   页码 482-492 doi: 10.1007/s11465-018-0505-y

摘要:

This paper presents our latest work on comprehensive modeling of process-structure-property relationships for additive manufacturing (AM) materials, including using data-mining techniques to close the cycle of design-predict-optimize. To illustrate the process-structure relationship, the multi-scale multi-physics process modeling starts from the micro-scale to establish a mechanistic heat source model, to the meso-scale models of individual powder particle evolution, and finally to the macro-scale model to simulate the fabrication process of a complex product. To link structure and properties, a high-efficiency mechanistic model, self-consistent clustering analyses, is developed to capture a variety of material response. The model incorporates factors such as voids, phase composition, inclusions, and grain structures, which are the differentiating features of AM metals. Furthermore, we propose data-mining as an effective solution for novel rapid design and optimization, which is motivated by the numerous influencing factors in the AM process. We believe this paper will provide a roadmap to advance AM fundamental understanding and guide the monitoring and advanced diagnostics of AM processing.

关键词: additive manufacturing     thermal fluid flow     data mining     material modeling    

Radiative properties of materials with surface scattering or volume scattering: A review

Qunzhi ZHU, Hyunjin LEE, Zhuomin M. HANG

《能源前沿(英文)》 2009年 第3卷 第1期   页码 60-79 doi: 10.1007/s11708-009-0011-3

摘要: Radiative properties of rough surfaces, particulate media and porous materials are important in thermal engineerit transfer between surfaces and volume elements in participating media, as well as for accurate radiometric temperature measurements. In this paper, recent research on scattering of thermal radiation by rough surfaces, fibrous insulation, soot, aerogel, biological materials, and polytetrafluoroethylene (PTFE) was reviewed. Both theoretical modeling and experimental investigation are discussed. Rigorous solutions and approximation methods for surface scattering and volume scattering are described. The approach of using measured surface roughness statistics in Monte Carlo simulations to predict radiative properties of rough surfaces is emphasized. The effects of various parameters on the radiative properties of particulate media and porous materials are summarized.

关键词: aerogel     fiber     particle scattering     radiative properties     soot     surface roughness    

Self-sacrificial templating synthesis of flower-like nickel phyllosilicates and its application as high-performance reinforcements in epoxy nanocomposites

《化学科学与工程前沿(英文)》 2022年 第16卷 第4期   页码 484-497 doi: 10.1007/s11705-021-2074-6

摘要: The nanocomposites of flower-like nickel phyllosilicate particles incorporated into epoxy resin were fabricated via an in-situ mixing process. The flower-like nickel phyllosilicate particles were firstly synthesized using a mild self-sacrificial templating method, and the morphology and lamellar structure were examined carefully. Several properties of mechanical, thermal and tribological responses of epoxy nanocomposites were performed. It was demonstrated that adequate flower-like nickel phyllosilicate particles dispersed well in the matrix, and the nanocomposites displayed enhanced tensile strength and elastic modulus but decreased elongation at break as expected. In addition, friction coefficient and wear rate were increased first and then decreased along with the particle content, and showed the lowest values at a mass fraction of 5%. Nevertheless, the incorporated flower-like nickel phyllosilicate particles resulted in the continuously increasing thermal stability of epoxy resin (EP) nanocomposites. This study revealed the giant potential of flower-like particles in preparing high-quality EP nanocomposites.

关键词: nickel phyllosilicate     flow-like structure     mechanical property     thermal stability     tribological performance    

标题 作者 时间 类型 操作

Thermal radiative properties of metamaterials and other nanostructured materials: A review

Ceji FU, Zhuomin M. ZHANG

期刊论文

novel strategy for the construction of silk fibroin–SiO composite aerogel with enhanced mechanical propertyand thermal insulation performance

期刊论文

Adsorption property of direct fast black onto acid-thermal modified sepiolite and optimization of adsorption

Chengyuan SU, Weiguang LI, Yong WANG

期刊论文

Thermal performance of a single-layer packed metal pebble-bed exposed to high energy fluxes

Shengchun ZHANG, Zhifeng WANG, Hui BIAN, Pingrui HUANG

期刊论文

Dielectric property of polyimide/barium titanate composites and its influence factors (II)

LIU Weidong, ZHU Baoku, XIE Shuhui, XU Zhikang

期刊论文

基于蝶翅三级微纳米结构的定制光子工程辐射制冷纺织品

郭竑宇, 牛田野, 俞建勇, 王学利, 斯阳

期刊论文

of hierarchical nanohybrid CNT@Ni-PS and its applications in enhancing the tribological, curing and thermal

Jinian Yang, Yuxuan Xu, Chang Su, Shibin Nie, Zhenyu Li

期刊论文

Microdamage study of granite under thermomechanical coupling based on the particle flow code

期刊论文

A spectrally selective surface structure for combined photothermic conversion and radiative sky cooling

Bin ZHAO, Xianze AO, Nuo CHEN, Qingdong XUAN, Mingke HU, Gang PEI

期刊论文

用于个人降温和保暖的具有定制热传导和热辐射特性的双功能非对称织物

Yucan Peng, Hiang Kwee Lee, David S. Wu, Yi Cui

期刊论文

Entropy flow, entropy generation, exergy flux, and optimal absorbing temperature in radiative transfer

Zeshao CHEN, Songping MO, Peng HU, Shouli JIANG, Gang WANG, Xiaofang CHENG,

期刊论文

Modeling radiative effects of haze on summer-time convective precipitation over North China: a case study

Xuying WANG, Bin ZHANG

期刊论文

Modeling process-structure-property relationships for additive manufacturing

Wentao YAN, Stephen LIN, Orion L. KAFKA, Cheng YU, Zeliang LIU, Yanping LIAN, Sarah WOLFF, Jian CAO, Gregory J. WAGNER, Wing Kam LIU

期刊论文

Radiative properties of materials with surface scattering or volume scattering: A review

Qunzhi ZHU, Hyunjin LEE, Zhuomin M. HANG

期刊论文

Self-sacrificial templating synthesis of flower-like nickel phyllosilicates and its application as high-performance reinforcements in epoxy nanocomposites

期刊论文